Au(111)
on mica(order
from here)
⇒保原大介:真空蒸着法による(111)単結晶面をもつ金薄膜の
作製方法
⇒原
正彦 (理研):マイ
カ上のAu(111)単結晶基板―その作製法と表面再配列構造の最近の話題―
JSTAGE:
表
面科学 21, No.11 724-730 2000.
⇒mica上の金へのflame annealing M.H.
Dishner et al. J. Vac. Sci. Technol. A 16 3295-3300 (1998)
⇒mica上へのultra-flat
film(two step deposition) B.
Lussem et al. Appl. Surf. Sci. 249 197-202 (2005)
(1) a single step process with a constant deposition rate
(0.1 nm/s)
(2) a
two-step deposition process,
where a 150 nm gold film is deposited at a
high rate (5 nm/s)
followed by a 50 nm gold film at a considerably
reduced rate (0.05 nm/s).
Prior to deposition, mica is freshly cleaved and
then heated in vacuum for 6 h at the
deposition temperature
(460 °C for (1), 400 °C for (2)).
Following the deposition the
films are annealed
for 1 h at the deposition temperature.
The single step deposition process results in a film
of many small (1–2 μm) grains with a hexagonal shape.
Using the two-step deposition process introduced
here the growth of the
gold film can be changed from island
to two-dimensional growth due to
the improved wetting forced by the higher deposition rate in the first
step.
The extremely low deposition rate in the
second step causes a
flattening of the surfaces by filling up the
remaining trenches of the
first step.. The
resulting gold films exhibit
a very low
roughness on a large surface
area (0.4 nm r.m.s. on 5 μm × 5 μm).
From UHV-STM scans
large atomically flat gold terraces
(100–300 nm width)
and two distinct
structures can be seen: facets with linear step edges along the (01-1)
directions and structures
with rounded step edges.